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Hydrogen-generating technology shows advances in development of clean energy carrier

30 08 07 - 07:25


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Hydrogen-generating technology shows advances in development of clean energy carrier


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W. Lafayette, IN - Ongoing research at Purdue is showing advances in hydrogen-generating technology with a recent breakthrough aluminum and gallium alloy that contains more of the aluminum which breaks water molecules down, releasing the hydrogen gas for power generation.

The technology produces hydrogen by adding water to an alloy of aluminum and gallium. When water is added to the alloy, the aluminum splits water by attracting oxygen, liberating hydrogen in the process. The Purdue researchers are developing a method to create particles of the alloy that could be placed in a tank to react with water and produce hydrogen on demand. Hydrogen-generating technology shows advances in development of clean energy carrier


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W. Lafayette, IN - Ongoing research at Purdue is showing advances in hydrogen-generating technology with a recent breakthrough aluminum and gallium alloy that contains more of the aluminum which breaks water molecules down, releasing the hydrogen gas for power generation.

The technology produces hydrogen by adding water to an alloy of aluminum and gallium. When water is added to the alloy, the aluminum splits water by attracting oxygen, liberating hydrogen in the process. The Purdue researchers are developing a method to create particles of the alloy that could be placed in a tank to react with water and produce hydrogen on demand.

The gallium is a critical component because it hinders the formation of an aluminum oxide skin normally created on aluminum's surface after bonding with oxygen, a process called oxidation. This skin usually acts as a barrier and prevents oxygen from reacting with aluminum. Reducing the skin's protective properties allows the reaction to continue until all of the aluminum is used to generate hydrogen, said Jerry Woodall, a distinguished professor of electrical and computer engineering at Purdue who invented the process.

Since the technology was first announced in May, researchers have developed an improved form of the alloy that contains a higher concentration of aluminum.

Recent findings are detailed in the first research paper about the work, which will be presented on Sept. 7 during the 2nd Energy Nanotechnology International Conference in Santa Clara, Calif. The paper was written by Woodall, Charles Allen and Jeffrey Ziebarth, both doctoral students in Purdue's School of Electrical and Computer Engineering.

Because the technology could be used to generate hydrogen on demand, the method makes it unnecessary to store or transport hydrogen - two major obstacles in creating a hydrogen economy, Woodall said.

The gallium component is inert, which means it can be recovered and reused.

"This is especially important because of the currently much higher cost of gallium compared with aluminum," Woodall said. "Because gallium can be recovered, this makes the process economically viable and more attractive for large-scale use. Also, since the gallium can be of low purity, the cost of impure gallium is ultimately expected to be many times lower than the high-purity gallium used in the electronics industry."

As the alloy reacts with water, the aluminum turns into aluminum oxide, also called alumina, which can be recycled back into aluminum. The recycled aluminum would be less expensive than mining the metal, making the technology more competitive with other forms of energy production, Woodall said.

In recent research, the engineers rapidly cooled the molten alloy to make particles that were 28 percent aluminum by weight and 72 percent gallium by weight. The result was a "metastable solid alloy" that also readily reacted with water to form hydrogen, alumina and heat, Woodall said.

Following up on that work, the researchers discovered that slowly cooling the molten alloy produced particles that contain 80 percent aluminum and 20 percent gallium.

"Particles made with this 80-20 alloy have good stability in dry air and react rapidly with water to form hydrogen," Woodall said. "This alloy is under intense investigation, and, in our opinion, it can be developed into a commercially viable material for splitting water."

The technology has numerous potential applications. Because the method makes it possible to use hydrogen instead of gasoline to run internal combustion engines, it could be used for cars and trucks. Combusting hydrogen in an engine or using hydrogen to drive a fuel cell produces only water as waste.

"It's a simple matter to convert ordinary internal combustion engines to run on hydrogen. All you have to do is replace the gasoline fuel injector with a hydrogen injector," Woodall said.

The U.S. Department of Energy has set a goal of developing alternative fuels that possess a "hydrogen mass density" of 6 percent by the year 2010 and 9 percent by 2015. The percent mass density of hydrogen is the mass of hydrogen contained in the fuel divided by the total mass of the fuel multiplied by 100. Assuming 50 percent of the water produced as waste is recovered and cycled back into the reaction, the new 80-20 alloy has a hydrogen mass density greater than 6 percent, which meets the DOE's 2010 goal.

Aluminum is refined from the raw mineral bauxite, which also contains gallium. Producing aluminum from bauxite results in waste gallium.

"This technology is feasible for commercial use," Woodall said. "The waste alumina can be recycled back into aluminum, and low-cost gallium is available as a waste product from companies that produce aluminum from the raw mineral bauxite. Enough aluminum exists in the United States to produce 100 trillion kilowatt hours of energy. That's enough energy to meet all the U.S. electric needs for 35 years. If impure gallium can be made for less than $10 a pound and used in an onboard system, there are enough known gallium reserves to run 1 billion cars."

The researchers note in the paper that for the technology to be used to operate cars and trucks, a large-scale recycling program would be required to turn the alumina back into aluminum and to recover the gallium.

"In the meantime, there are other promising potential markets, including lawn mowers and personal motor vehicles such as golf carts and wheelchairs," Woodall said. "The golf cart of the future, three or four years from now, will have an aluminum-gallium alloy. You will add water to generate hydrogen either for an internal combustion engine or to operate a fuel cell that recharges a battery. The battery will then power an electric motor to drive the golf cart."

Another application that is rapidly being developed is for emergency portable generators that will use hydrogen to run a small internal combustion engine. The generators are likely to be on the market within a year, Woodall said.

The technology also could make it possible to introduce a non-polluting way to idle diesel trucks. Truck drivers idle their engines to keep power flowing to appliances and the heating and air conditioning systems while they are making deliveries or parked, but such idling causes air pollution, which has prompted several states to restrict the practice.

The new hydrogen technology could solve the truck-idling dilemma.

"What we are proposing is that the truck would run on either hydrogen or diesel fuel," Woodall said. "While you are on the road you are using the diesel, but while the truck is idling, it's running on hydrogen."

The new hydrogen technology also would be well-suited for submarines because it does not emit toxic fumes and could be used in confined spaces without harming crew members, Woodall said.

"You could replace nuclear submarines with this technology," he said.

Other types of boats, including pleasure craft, also could be equipped with such a technology.

"One reason maritime applications are especially appealing is that you don't have to haul water," Woodall said.

The Purdue researchers had thought that making the process competitive with conventional energy sources would require that the alumina be recycled back into aluminum using a dedicated infrastructure, such as a nuclear power plant or wind generators. However, the researchers now know that recycling the alumina would cost far less than they originally estimated, using standard processing already available.

"Since standard industrial technology could be used to recycle our nearly pure alumina back to aluminum at 20 cents per pound, this technology would be competitive with gasoline," Woodall said. "Using aluminum, it would cost $70 at wholesale prices to take a 350-mile trip with a mid-size car equipped with a standard internal combustion engine. That compares with $66 for gasoline at $3.30 per gallon. If we used a 50 percent efficient fuel cell, taking the same trip using aluminum would cost $28."

The Purdue Research Foundation holds title to the primary patent, which has been filed with the U.S. Patent and Trademark Office and is pending. An Indiana startup company, AlGalCo LLC., has received a license for the exclusive right to commercialize the process.

In 1967, while working as a researcher at IBM, Woodall discovered that liquid alloys of aluminum and gallium spontaneously produce hydrogen if mixed with water. The research, which focused on developing new semiconductors for computers and electronics, led to advances in optical-fiber communications and light-emitting diodes, making them practical for everything from DVD players to television remote controls and new types of lighting displays. That work also led to development of advanced transistors for cell phones and components in solar cells powering space modules like those used on the Mars rover, earning Woodall the 2001 National Medal of Technology from President George W. Bush.

Also while at IBM, Woodall and research engineer Jerome Cuomo were issued a U.S. patent in 1982 for a "solid state, renewable energy supply." The patent described their discovery that when aluminum is dissolved in liquid gallium just above room temperature, the liquid alloy readily reacts with water to form hydrogen, alumina and heat.

Future research will include work to further perfect the solid alloy and develop systems for the controlled delivery of hydrogen. Used tags: , , ,

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Raging wildfires: Climate changes to blame for record season?

Saturday 16 July 2011 at 06:07 am Raging wildfires: Climate changes to blame for record season?


By Pete Spotts


The images are stark: soot-grimed firefighters steering bulldozers or wielding shovels to clear underbrush; curtains of orange flame tracing the contours of summits; aircraft dumping chemicals to slow a fire's progress.

Between Jan. 1 and early July of 2011, slightly more than 38,000 wildfires charred the landscape in the United States at a record pace. So far this year, wildfires have consumed just under 4.9 million acres of forest and grassland, a cumulative expanse the size of New Jersey.

That's 1 million more acres than fires consumed during the same period in 2006, which saw a record 9.9 million acres burned for the entire year.

Beyond the numbers, this year's fires may provide the first large-scale tests of the effectiveness of projects undertaken over the past decade to help forests survive wildfires, several specialists say.

The West's forests are adapted to deal with certain types of wildfires, researchers note. But since the mid-1980s, they add, some of these forests have experienced an increasing number of fires to which they are not well adapted.

Many researchers trace this shift in part to climate change. more

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Sunday 22 May 2011 at 01:14 am Hybrid Moves Into Housing


By Brenda Krueger Huffman

(Chicago) – Recycling - Check. Conserving energy - Check. Hybrid car - Next car, check. Hybrid home system - What? Yes, it’s here. Hybrid has seamlessly, successfully moved into housing.

Safety Power, Inc. was initially started to provide homes with back up power. The company quickly grew to include renewable energy options and advising commercial and industrial clients with electrical conservation. Recently the company has come full circle and began marketing a new more capable type of renewable energy system for homes.

The award winning firm was voted one of the “Top 5 Sustainable Product Companies in Illinois” and continues to grow its residential client base in Illinois, Indiana, and Wisconsin. Safety Power also serves larger firms on the national level.

Robert Brazzale, President of Safety Power, a master electrician turned entrepreneur, began Safety Power in 2007. An avid member of Local First Chicago, Rob believes in assisting sustaining local economies with green collar jobs and belongs to many green orientated groups in Chicago and around the country. more

Are electric car makers missing the trick?

Tuesday 29 March 2011 at 11:12 am Are electric car makers missing the trick?


by Martin Ott

I believe that electric car makers may be driving us all down the road that may result in the same sort of technology failures that we have seen in the past.
I'm not referring to the Sinclair scooter here but cast your mind back to the débâcle of Betamax v VHS home recording systems. The eventual winner was the technically inferior VHS but the battle was not resolved until innumerable consumers had paid out for worthless Betamax systems. Back in the 70's a similar conflict occurred over audio systems when America fell in love with the 8 track tape system that moved magnetic tape in a loop over the player head at a high speed resulting in a better sound. The world market finally dictated that the audio cassette was the way to go but not until millions of consumers had been lumbered with home and in-car systems that went down the technological cul de sac. more

Wind Turbine Manufacturer Acknowledges SGS´s Contribution towards Successful Project Completion

Tuesday 29 March 2011 at 10:57 am by Suresh Varma

The Theni Wind Farm project was developed by CLP India Pvt. Ltd., one of the major wind farm project developers in India. Located in the south western part of Tamilnadu, a southern state of the country, the facility consists of 60 Vestas V82 geared wind turbines. As recognition of its contribution towards the successful execution of this wind power project SGS received Vestas award.

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Acting as contract engineer during project execution, SGS was responsible for ensuring that all activities were carried out at the site by the contractor in line with the final agreement. In doing so, SGS supervised the quality of construction works, the fulfillment of the technical parameters and kept the project within the scheduled time and contracted price. more

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by Power Plus Communications

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Using BPL technology, standard compliant and IP-based data transfer rates of 5-30 Mbit/s can easily be achieved via the medium voltage cable itself. Within E.ON’s smart grid project, PPC's medium voltage technology facilitated the extension of Cisco's Connected Grid Solution. The Cisco smart grid Router and Switches used in the project are highly compatible with BPL networks, providing a real cost advantage over fiber optic networks – which can be much more expensive where cables are not pre-existing.

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Chicago – Perhaps moving to the center is where we all need to be politically on the environment and effective spending compatibility. Not all green technology is crazy, and not all business profit or government expenditure is evil.

Even if you do not believe in man caused climate change, we can all agree leaving a cleaner planet and a more fiscally responsible government for the next generation is preferable to not doing so.

Perhaps green technology can be cost effective, and government fiscal responsibility may realistically include affordable green initiatives. Honest “life cycle analysis” and “life cycle cost analysis” study considerations should be a political compromise starting point both the left and the right can embrace. more

Global warming: Impact of receding snow and ice surprises scientists

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By Pete Spotts


Washington - A long-term retreat in snow and ice cover in the Northern Hemisphere is weakening the ability of these seasonal cloaks of white to reflect sunlight back into space and cool global climate, according to a study published this week.

Indeed, over the past 30 years, the cooling effect from this so-called cryosphere – essentially areas covered by snow and ice at least part of the year – appears to have weakened at more than twice the pace projected by global climate models, the research team conducting the work estimates.

The study, which appeared online Sunday in the journal Nature Geoscience, represents a first cut at trying to calculate from direct measurements the impact of climate change on the Northern Hemisphere's cryosphere. The study was conducted by a team of federal and university scientists who examined data gathered between 1979 and 2008. more

EPA presents plan on greenhouse gases

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Washington - Setting the stage for a New Year battle royal between Congress and the White House over greenhouse gas emissions, the US Environmental Protection Agency Thursday laid out a timetable for the nation's largest carbon emitters – power plants and refineries – to begin curbing those pollutants.

Republicans have said all year that they plan to pull out all the stops to keep the EPA from phasing in greenhouse gas (GHG) regulations beginning in 2011, saying they would damage the energy industry, raise prices, and cost jobs.

Rep. Fred Upton (R) of Michigan, the incoming chairman of the House Energy and Commerce Committee, has said he opposes the regulations on greenhouse gases and indicated he would lead efforts to revoke EPA regulations in the next Congress. The new regulations, he says, will likely lead to the shut down of coal-fired power plants.

"To protect jobs and fortify our energy security, we should be working to bring more power online, not shutting plants down," Mr. Upton said in a statement. "We are woefully unprepared to meet our nation's growing energy demands, yet this administration's 'none of the above' energy policy will do nothing but cost jobs, make energy more expensive, and increase our dependence on foreign sources of energy."

Environmentalists lauded the EPA's move. more

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Washington - The US Supreme Court on Monday agreed to examine a major environmental lawsuit that seeks to force six electric power companies to cap and reduce their carbon-dioxide emissions to fight global warming.

The lawsuit - filed in 2004 by eight states, the City of New York, and three land trusts - targets what it claims are the largest emitters of carbon dioxide in the United States and among the largest in the world.

It seeks a judicial order declaring that the fossil-fueled power plants are a "public nuisance." It also seeks a judicial order capping the plants' greenhouse gas emissions and requiring the plants to adopt a schedule of reduced emissions in future years. more

Outside Cancun climate conference, Caribbean Sea testifies to global warming

Monday 13 December 2010 at 03:09 am By Ezra Fieser,


Bayahibe, Dominican Republic - This summer's extreme heat may seem like a distant memory as winter approaches the United States.

But the summer that broke heat records across the Northern Hemisphere is still being felt below the surface of the Caribbean Sea: 2010 will likely be one of the most deadly years on record for coral reefs.

If diplomats attending the two-week global climate change talks that opened Monday in Cancun, Mexico, want more evidence of the negative and potentially devastating affects of warming temperatures, they need look no further than the blue sea outside their hotels. Researchers say that throughout the Caribbean coral reefs are "bleaching," a condition that occurs when they are under extreme stress due to warmer-than-normal sea temperatures. more